Magneto-optic trap using a reversible, solid-state alkali-metal source.

We demonstrate a novel way to form and deplete a vapor-cell magneto-optic trap (MOT) using a reversible, solid-state alkali-metal source via an applied polarized voltage. Using ∼100 mW of electrical power, a trapped-atom number of 5×106 has been achieved, starting from near zero and the timescales of the MOT formation and depletion of ∼1 s. This fast, reversible, and low-power alkali-atom source is desirable in both tabletop and portable cold-atom systems. The core technology of this device should translate readily to other alkali and alkaline-earth elements that could find a wide range of uses in cold-atom systems and instruments.

Ramsey Spectroscopy with Displaced Frequency Jumps.

Sophisticated Ramsey-based interrogation protocols using composite laser pulse sequences have been recently proposed to provide next-generation high-precision atomic clocks with a near perfect elimination of frequency shifts induced during the atom-probing field interaction. We propose here a simple alternative approach to the autobalanced Ramsey interrogation protocol and demonstrate its application to a cold-atom microwave clock based on coherent population trapping (CPT). The main originality of the method, based on two consecutive Ramsey sequences with different dark periods, is to sample the central Ramsey fringes with frequency jumps finely adjusted by an additional frequency-displacement concomitant parameter, scaling as the inverse of the dark period. The advantage of this displaced frequency-jump Ramsey method is that the local oscillator (LO) frequency is used as a single physical variable to control both servo loops of the sequence, simplifying its implementation and avoiding noise associated with controlling the LO phase. When tested using a CPT cold-atom clock, the DFJR scheme reduces the sensitivity of the clock frequency to variations of the light shifts by more than an order of magnitude compared with the standard Ramsey interrogation. This simple method can be applied in a wide variety of Ramsey-spectroscopy based applications including frequency metrology with CPT-based and optical atomic clocks, mass spectrometry, and precision spectroscopy.

High-accuracy measurement of the blackbody radiation frequency shift of the ground-state hyperfine transition in 133Cs.

We report a high-accuracy direct measurement of the blackbody radiation shift of the 133Cs ground-state hyperfine transition. This frequency shift is one of the largest systematic frequency biases encountered in realizing the current definition of the International System of Units (SI) second. Uncertainty in the blackbody radiation frequency shift correction has led to its being the focus of intense theoretical effort by a variety of research groups. Our experimental measurement of the shift used three primary frequency standards operating at different temperatures. We achieved an uncertainty a factor of five smaller than the previous best direct measurement. These results tend to validate the claimed accuracy of the recently calculated values.

Offset phase locking of noisy diode lasers aided by frequency division.

For heterodyne phase locking, frequency division of the beat note between two oscillators can improve the reliability of the phase lock and the quality of the phase synchronization. Frequency division can also reduce the size, weight, power, and cost of the instrument by excluding the microwave synthesizer from the control loop when the heterodyne offset frequency is large (5 to 10 GHz). We have experimentally tested the use of a frequency divider in an optical phase-lock loop and compared the achieved level of residual phase fluctuations between two diode lasers with that achieved without the use of a frequency divider. The two methods achieve comparable phase stability provided that sufficient loop gain is maintained after frequency division to preserve the required bandwidth. We have also numerically analyzed the noise properties and internal dynamics of phase-locked loops subjected to a high level of phase fluctuations, and our modeling confirms the expected benefits of having an in-loop frequency divider.

Demonstration of high-performance compact magnetic shields for chip-scale atomic devices.

We have designed and tested a set of five miniature nested magnetic shields constructed of high-permeability material, with external volumes for the individual shielding layers ranging from 0.01 to 2.5 cm(3). We present measurements of the longitudinal and transverse shielding factors (the ratio of external to internal magnetic field) of both individual shields and combinations of up to three layers. The largest shielding factor measured was 6 x 10(6) for a nested set of three shields, and from our results we predict a shielding factor of up to 1 x 10(13) when all five shields are used. Two different techniques were used to measure the internal field: a chip-scale atomic magnetometer and a commercially available magnetoresistive sensor. Measurements with the two methods were in good agreement.

Single-atom optical clock with high accuracy.

For the past 50 years, atomic standards based on the frequency of the cesium ground-state hyperfine transition have been the most accurate time pieces in the world. We now report a comparison between the cesium fountain standard NIST-F1, which has been evaluated with an inaccuracy of about 4 x 10(-16), and an optical frequency standard based on an ultraviolet transition in a single, laser-cooled mercury ion for which the fractional systematic frequency uncertainty was below 7.2 x 10(-17). The absolute frequency of the transition was measured versus cesium to be 1,064,721,609,899,144.94 (97) Hz, with a statistically limited total fractional uncertainty of 9.1 x 10(-16) the most accurate absolute measurement of an optical frequency to date.

Measurement of dynamic end-to-end cavity phase shifts in cesium-fountain frequency standards.

We have measured a previously unobserved systematic frequency shift in our cesium-fountain frequency standard, NIST-F1. This shift, predicted theoretically previously, mimics the well-known end-to-end phase shift in atomic beam standards when synchronous thermal transients are present. Detuning the microwave cavity several megahertz from resonance reduces this effect to the deltaf/f = 1o(-16) level.

Microscopic dynamics in a strongly interacting Bose-Einstein condensate.

An initially stable 85Rb Bose-Einstein condensate (BEC) was subjected to a carefully controlled magnetic field pulse near a Feshbach resonance. This pulse probed the strongly interacting regime for the BEC, with the diluteness parameter (na(3)) ranging from 0.01 to 0.5. Condensate number loss resulted from the pulse, and for triangular pulses shorter than 1 ms, decreasing the pulse length actually increased the loss, until very short time scales (approximately 10 micros) were reached. The observed time dependence is very different from that expected in traditional inelastic loss processes, suggesting the presence of new microscopic BEC physics.

Dynamics of collapsing and exploding Bose-Einstein condensates.

When atoms in a gas are cooled to extremely low temperatures, they will-under the appropriate conditions-condense into a single quantum-mechanical state known as a Bose-Einstein condensate. In such systems, quantum-mechanical behaviour is evident on a macroscopic scale. Here we explore the dynamics of how a Bose-Einstein condensate collapses and subsequently explodes when the balance of forces governing its size and shape is suddenly altered. A condensate's equilibrium size and shape is strongly affected by the interatomic interactions. Our ability to induce a collapse by switching the interactions from repulsive to attractive by tuning an externally applied magnetic field yields detailed information on the violent collapse process. We observe anisotropic atom bursts that explode from the condensate, atoms leaving the condensate in undetected forms, spikes appearing in the condensate wavefunction and oscillating remnant condensates that survive the collapse. All these processes have curious dependences on time, on the strength of the interaction and on the number of condensate atoms. Although the system would seem to be simple and well characterized, our measurements reveal many phenomena that challenge theoretical models.

Electronic energy relaxation and transition frequency jumps of single molecules at 30 mK.

Transition frequency jumps for single terrylene molecules in a polyethylene matrix caused by resonant laser irradiation are investigated at 30 mK. These jumps are not accompanied by substantial sample heating. A model for the effect is proposed, based on the interaction of tunneling two-level systems (TLSs) surrounding the single molecule with high-energy nonthermal phonons emitted by the molecule during electronic energy relaxation. The radius of the effective interaction volume is estimated to be r(m) approximately 12.5 nm, and the interaction cross section for nonequilibrium phonon-TLS scattering is estimated as approximately 10(-22) cm2.

Controlled collapse of a Bose-Einstein condensate.

The point of instability of a Bose-Einstein condensate (BEC) due to attractive interactions was studied. Stable 85Rb BECs were created and then caused to collapse by slowly changing the atom-atom interaction from repulsive to attractive using a Feshbach resonance. At a critical value, an abrupt transition was observed in which atoms were ejected from the condensate. By measuring the onset of this transition as a function of number and attractive interaction strength, we determined the stability condition to be N(absolute value of a) / a(ho) = 0.459+/-0.012+/-0.054, slightly lower than the predicted value of 0.574.

Single-molecule spectroscopy.

Recent experimental and theoretical studies concerning single-molecule spectroscopy in solids are discussed. Pure quantum effects--such as photon bunching, antibunching, and spectral jumps--and more classical phenomena--such as near-field excitation, saturation, ac/dc Stark shifts, spectral diffusion, two-photon excitation, and customary spectroscopic analysis--are considered. The emphasis of this review is on physical results and their interpretation. This is preceded by a general introduction, where fundamentals of single-molecule spectroscopy are explained.